Hastelloy vs. Zirconium for HCl with Contaminants

Q: I have a process that utilizes about 10% hydrochloric acid with trace amounts of other chemicals. I tried zirconium bolts because they are known for HCl but we’re burning through them like crazy and I can’t figure out why they are corroding. Any ideas and what other material may work?

A: I think the key to what you are describing is not the hydrochloric acid corrosion but the “other chemicals” in your process. Zirconium bolts offer excellent resistance to HCl corrosion even upwards of 37%. The problem with zirconium fasteners is that if they are exposed to any oxidizing media. Oxidizers, even in trace amounts can cause zirconium to corrode rather quickly. Depending on the temperature of your process, Hastelloy C276 bolts will be a good fit. For a high temperature application, I would suggest tantalum fasteners. They can handle HCl corrosion even up to the boiling point.

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